Hydrological and biogeochemical processes controlling riparian groundwater quantity and quality during riverbank filtration.

Groundwater exploitation in a riparian zone causes water infiltration from the river into the aquifer. Owing to adsorption and redox reactions along the flow path, the quality of water flowing from the river to groundwater wells is variably altered. The riverbed composition often involves spatiotemporal differences due to frequent changes in hydrological conditions. These changes create uncertainties in the transport and removal of solutes in the river water. In this study, the hydrodynamic field associated with riparian groundwater, changes in the structure of riverbed sediments caused by erosion and deposition, fluctuations in surface water and groundwater levels, and the removal efficiency of pollutants from groundwater through pumping were investigated. This involved in situ monitoring and sample testing of the composition of the river water, riverbed sediments, riverbed pore water, and groundwater during dry and wet seasons. Implementation of field in situ column experiments and molecular biology evidences were conducive to identifying the main biogeochemical processes occurring in the riverbed. The findings indicated that riparian groundwater exploitation alters the natural groundwater flow field, while fine sand deposition and microbial adsorption can reduce river recharge to aquifers by diminishing riverbed hydraulic conductivity. Shallow sediments within 1 m depth mainly involve NO3- reduction and E. coli adsorption. Reductive dissolution of Mn dominates in the deeper sediments. Additionally, reductive dissolution of Fe and dissimilatory nitrate reduction to ammonium (DNRA) drive high Fe2+ and NH4+ concentrations in groundwater. The findings can improve the management of riparian groundwater and aid in the optimization of a plan for its exploitation.

Driving mechanism of different nutrient conditions on microbial mediated nitrate reduction in magnetite-present river infiltration zone.

Significant research is focused on the ability of riparian zones to reduce groundwater nitrate contamination. Owing to the extremely high redox activity of nitrate, naturally existing electron donors, such as organic matter and iron minerals, are crucial in facilitating nitrate reduction in the riparian zone. Here, we examined the coexistence of magnetite, an iron mineral, and nitrate, a frequently observed coexisting system in sediments, to investigate nitrate reduction features at various C/N ratios and evaluate the response of microbial communities to these settings. Additionally, we aimed to use this information as a foundation for examining the effect of nutritional conditions on the nitrate reduction process in magnetite-present environments. These results emphasise the significance of organic matter in enabling dissimilatory nitrate reduction to ammonium (DNRA) and enhancing the connection between nitrate reduction and iron in sedimentary environments. In the later phases of nitrate reduction, nitrogen fixation was the prevailing process in low-carbon environments, whereas high-carbon environments tended to facilitate the breakdown of organic nitrogen. High-throughput sequencing analysis revealed a robust association between C/N ratios and alterations in microbial community composition, providing insights into notable modifications in essential functioning microorganisms. The nitrogen-fixing bacterium Ralstonia is more abundant in ecosystems with scarce organic matter. In contrast, in settings rich in organic matter, microorganisms, such as Acinetobacter and Clostridia, which may produce ammonia, play crucial roles. Moreover, the population of iron bacteria grows in such an environment. Hence, this study proposes that C/N ratios can influence Fe(II)/Fe(III) conversions and simultaneously affect the process of nitrate reduction by shaping the composition of specific microbial communities.

Soil ecoenzyme activities coupled with soil properties and plant biomass strongly influence the variation in soil organic carbon components in semi-arid degraded wetlands.

Wetland degradation can induce alterations in plant biomass, soil properties, and soil ecoenzyme activities, consequently influencing soil organic carbon components. Despite extensive investigations into the relationships among plant characteristics, soil properties, and soil organic carbon components, the enzymatic mechanisms underlying changes in soil organic carbon components, particularly the impact and contribution of ecoenzyme activities, remain poorly understood. This study compared the soil organic carbon components at a depth of 0-20 cm in wetlands in the semi-arid western Songnen Plain under different degradation levels and explored plant biomass, soil properties, and soil ecoenzyme activities. The results showed that the soil total organic carbon, labile organic carbon, and recalcitrant organic carbon contents in the degraded wetlands were generally lower than those in the non-degraded wetlands. Furthermore, the soil nutrient contents and soil ß-1,4-glucosidase, L-leucine aminopeptidase, and acid phosphatase activities were also lower in the degraded wetlands than in the non-degraded wetlands. Vector analysis of enzymatic stoichiometry revealed that wetland degradation did not increase microbial carbon limitation. The soil organic carbon components showed significant positive correlations with plant biomass, soil water content, soil total nitrogen, soil total phosphorus, as well as soil ecoenzyme activities. Variation partitioning analysis revealed that plant biomass, soil properties, soil ecoenzyme activities collectively accounted for 78.5 % variation in soil organic carbon components, among which plant biomass, soil properties, soil ecoenzyme activities, and their interactions explaining 4.2 %, 8.0 %, 7.9 %, and 24.5 % of the variation, respectively. Therefore, the impact of soil ecoenzyme activities and soil properties on soil organic carbon component changes was greater than that of plant biomass, with the interaction of these three factors playing a crucial role in soil organic carbon formation. This study provides a theoretical basis for scientifically evaluating the carbon sink function of degraded wetland soil and preserving the wetland soil carbon pool.

Hydrogeochemical changes during artificial groundwater well recharge.

Artificial groundwater recharge is a relatively economic and efficient method for solving shortages and uneven spatial-temporal distribution of water resources. Changes in groundwater quality during the recharge process are a key issue that must be addressed. Identifying the hydrogeochemical reactions that occur during recharge can be vital in predicting trends in groundwater quality. However, there are few studies on the evolution of groundwater quality during artificial recharge that comprehensively consider environmental, chemical, organic matter, and microbiological indicators. Based on an artificial groundwater recharge experiment in Xiong'an New Area, this study investigated the hydrogeochemical changes during groundwater recharge through a well. The results indicate that (1) as large amounts of recharge water (RW) were injected, the groundwater level initially rose rapidly, then fluctuated slowly, and finally rose again. (2) Water quality indicators, dissolved organic matter (DOM), and microbial communities were influenced by the mixture of RW and the background groundwater before recharge (BGBR), as well as by water-rock interactions, such as mineral dissolution-precipitation and redox reactions. (3) During well recharge, aerobic respiration, nitrification, denitrification, high-valence manganese (Mn) and iron (Fe) minerals reduction dissolution, and Mn2+ and Fe2+ oxidation-precipitation occurred sequentially. (4) DOM analysis showed that protein-like substances in the BGBR were the main carbon sources for aerobic respiration and denitrification, while humic-like substances carried by the RW significantly enhanced Mn and Fe minerals reduction dissolution. Therefore, RW quality significantly affects groundwater quality after artificial groundwater well recharge. Controlling indicators, such as dissolved oxygen (DO) and DOM, in the RW can effectively reduce harm to groundwater quality after recharge. This study is of theoretical and practical significance for in-depth analysis of the evolution of groundwater quality during artificial well recharge, prediction of trends in groundwater quality during and after recharge and ensuring groundwater quality safety.

Non-metal activated peroxydisulfate by straw biochar for tetracycline hydrochloride oxidative degradation: catalytic activity and mechanism.

In this study, stalk biochar (BC) was prepared by a high-temperature pyrolysis process and used as a non-metallic catalyst to activate peroxydisulfate (PDS) to degrade tetracycline hydrochloride (TCH). Various characterization results showed that BC had a hollow tubular structure, irregular folds, and important active sites such as oxygen-containing functional groups. Under the optimal reaction conditions, the degradation rate of TCH reached 98.1% within 120 min. In addition, the degradation performance was satisfactory and similar under acidic and near neutral pH, and higher temperature promoted the degradation of TCH. The SO4·-, ·OH, and 1O2 generated by PDS activation were reactive oxygen species (ROS), which degraded TCH through free radical/non-radical synergistic pathways. Quenching experiments proved that the generated SO4·- and ·OH might be the dominant reactive oxygen species (ROS) during the oxidative reaction. The research results will provide a theoretical basis for the application of PDS activated by non-metallic catalysts in the remediation of tetracycline antibiotics pollution.

Quantifying the effect of the nitrogen biogeochemical processes on the distribution of ammonium in the riverbank filtration system.

Ammonium (NH4+) enrichment of riverbank filtration (RBF) systems is gaining popularity. However, most previous research has concentrated on NO3- removal efficiencies, while the mechanisms of NH4+ enrichment remain unknown. A nitrogen biogeochemical process model was developed for the quantitative analysis of NH4+ enrichment in the Kaladian well field in northwest Songyuan City, NE China. Data from laboratory experiments and in-situ monitoring were used to determine initial values and calibrate the thermodynamic/kinetic parameters representing nitrogen (N) biogeochemical reactions. (1) The NO3- from river was subjected to denitrification (DNF) and dissimilatory nitrate reduction to ammonium (DNRA) within 10-14 m of the shore, whereas the NH4+ in groundwater was caused by DNRA, organic nitrogen mineralization (MIN), and mixing with laterally recharged high NH4+ groundwater. (2) DNF and DNRA were regulated by hydrodynamic processes, with the ranges of these processes being more significant in the wet season due to a higher hydraulic gradient. MIN occurred widely throughout the water flow path, with temperature primarily controlling the rates of the three reactions. (3) DNRA activity was relatively higher in the wet season when the water temperature was higher within 10-14 m of the shore. In the wet season, DNRA contributed 25%-30% to NO3- reduction, which was higher than in the dry season (5%-10%). DNRA contributed at least 40% and 15% to NH4+ enrichment in the wet and dry seasons, respectively. (4). Organic N in media gradually released NH4+ into groundwater via MIN and desorption across the entire flow path, with contributions to NH4+ enrichment reaching 75% and 85%, respectively, in the wet and dry seasons.

Mechanism of nitrogen-doped biochar activated peroxymonosulfate for degradation of 2,4-dichlorophenol.

Biochar activated peroxymonosulfate has been widely used to degrade organic pollutants. However, the chemical inertness of the sp2 hybrid conjugated carbon framework and the limited number of active sites on the pristine biochar resulted in the low catalytic activity of the system, restricting its further application. In this study, nitrogen-doped biochar was prepared following a simple one-step synthesis method taking advantage of the similar atomic radius and significant difference in electronegativity of N and C atoms to explore the properties and mechanisms of biochar-mediated peroxymonosulfate activation to degrade 2,4-dichlorophenol. Results from degradation experiments revealed that the catalytic efficiency of the prepared nitrogen-doped biochar was approximately 37.8 times higher than that of the undoped biochar. Quenching experiments combined with Electron paramagnetic resonance (EPR) analysis illustrated that the generated singlet oxygen (1O2) and superoxide anion radical (O2•-) were the main reactive oxidative species that dominated the target organics removal processes. This work will provide a theoretical basis for expanding the practical application of nitrogen-doped biochar to remediate water pollution via peroxymonosulfate activation.

Effects of magnetite on microbially driven nitrate reduction processes in groundwater.

Nitrate is a common pollutant in the aquatic environment. Denitrification and dissimilatory nitrate reduction to ammonium (DNRA) are the main reduction processes of nitrate. In the relatively closed sediment environment, the competitive interaction of these two nitrate reduction determines whether the ecosystem removes or retains nitrogen. In the process of NO3--N bioreduction, Magnetite, which is a common mineral present in soil and other sediments can play a crucial role. However, it is still not clear whether magnetite promotes or inhibits NO3--N bioreduction. In this paper, the effect of magnetite on NO3--N bioreduction was studied by batch experiments. The results show that magnetite can increase the NO3--N reduction rate by 1.48 %, and can inhibit the DNRA process at the beginning of the reaction and then promote the DNRA process. Magnetite changed the microbial community structure in our experiment systems. The relative abundance of Sphingomonas, which mainly exists in a high carbon and low nitrogen environment, increased under sufficient carbon source conditions. The relative abundance of Fe-oxidizing and NO3--N reducing bacteria, such as Flavobacterium, increased in the absence of carbon sources but in the presence of magnetite. In addition, magnetite can significantly increase activity of the microbial electron transport system (ETS). the added microbial electronic activity of magnetite increased nearly two-fold under the same experiment conditions. The acid produced by the metabolisms of Pseudomonas and Acinetobacter further promotes the dissolution of magnetite, thus increasing the concentration of Fe (II) in the system, which is beneficial to autotrophic denitrifying bacteria and promote the reduction of NO3--N. These findings can enhance our understanding of the interaction mechanism between iron minerals and nitrate reducing bacteria during nitrate reduction under natural conditions.

Effects of carbon load on nitrate reduction during riverbank filtration: Field monitoring and batch experiment.

Riverbank filtration (RBF) is a well-established technique worldwide, and is critical for the maintenance of groundwater quality and production of clean drinking water. Evaluation of the decay of exogenous nitrate (NO3-) in river water and the enrichment of ammonium (NH4+) in groundwater during RBF is important; these two processes are mainly influenced by denitrification (DNF) and dissimilatory nitrate reduction to ammonium (DNRA) controlled by the groundwater carbon load. In this study, the effects of carbon load (organic carbon [OC]: NO3-) on the competing nitrate reduction (DNRA and DNF) were assessed during RBF using field monitoring and a laboratory batch experiment. Results show the groundwater OC: NO3- ratio did not directly affect the reaction rate of DNRA and DNF, however, it could control the competitive partitioning between the two. In the near-shore zone, the groundwater OC: NO3- ratio shows significant seasonal variations along the filtration path owing to the changing conditions of redox, OC-rich, and NO3--limited. A greater proportion of NO3- would be available for DNRA in the wet season with higher OC: NO3- ratio (> 10), resulting in a significantly NH4+-N enrichment rate (from 1.43 × 10-3 to 9.54 × 10-4 mmol L-1 d-1) in the near-shore zone where the zone of Mn (IV) oxide reduction. However, the activity of DNRA was suppressed with lower OC: NO3- ratio (< 10) in the dry season, resulting in a stable NH4+-N enrichment rate (from 3.12 × 10-4 to 1.30 × 10-4 mmol L-1 d-1). Benefiting from seasonal variation of OC-rich and NO3--limited conditions, DNRA bacteria outcompeted denitrifiers, which eventually led to seasonal differences in NO3- reduction in the near-shore zone. Overall, under the effect of DNRA induced by continuous high carbon load in RBF systems, nitrogen input is not permanently removed but rather retained in groundwater during RBF.

Prediction and evaluation of groundwater level changes in an over-exploited area of the Baiyangdian Lake Basin, China under the combined influence of climate change and ecological water recharge.

Groundwater (GW) and surface water (SW) are important components of water resources and play key roles in social and economic development and regional ecological security. There are currently several stresses placing immense pressure on the GW resources of the Baiyangdian Lake Basin (BLB) in China, including climate change. A series of ecological and environmental challenges have manifested in the plain area of the BLB due to long-term over-exploitation of GW, including regional declines in GW level, aquifer drainage, land subsidence, and soil secondary salinization. Climate change may aggravate environmental challenges by altering GW recharge rates and availability of GW. This study applied the fully processed and physically-based numerical models, MODFLOW and the Soil & Water Assessment Tool (SWAT) in a semi-coupled modeling framework. The aim of the study was to quantitatively analyze changes to shallow GW levels and reserves in the plain area of BLB over the next 15 years (2021-2035) under climate change and different artificial recharge schemes. The results indicated that GW storage and levels are rising under the different GW recharge schemes. The maximum variation in the GW level was 20-30 m under a rainfall assurance rate of 50% and water level in the depression cone increased 14.20-14.98 m. This study can act as a theoretical basis for the development of a more sustainable GW management scheme in the plain area of the BLB and for the management and protection of aquifers in other areas with serious GW overdraft.

Nitrogen behavior during artificial groundwater recharge through ponds: A case study in Xiong'an New Area.

The Xiong'an New Area (XA) was established as a development hub in China. Excessive exploitation of groundwater has caused a series of environmental and geological problems, restricting further development of XA. The widely distributed ponds in this area have been targeted as convenient and efficient sites of artificial groundwater recharge. However, nitrogen accumulation in the shallow vadose zone associated with agricultural activities may pose environmental risks to groundwater during the recharge and infiltration process. Therefore, this study investigated the effects, transfer, and transformation of nitrogen during artificial groundwater recharge. The aeration zone is thick and the medium comprises fine particles, with total nitrogen and nitrate accumulation mainly in the shallow aeration zone. In indoor experiments, the nitrate removal rate reached 83.5% when organic carbon in the source water was increased by 10 mg/L. For Baigou diversion river water(BW) with slightly higher (14.46 mg/L) and lower (5.04 mg/L) nitrate contents, the nitrate content decreased by 26.0% (10.70 mg/L) and 26.8% (3.69 mg/L), respectively, after 150 days. When the water head was increased by 20 cm to increase the recharge rate, the time required for nitrate and ammonium to reach the maximum and equilibrium concentration was reduced by 50%. These findings indicate that nitrogen concentration in the source water, aeration zone media, and groundwater should be considered in pond replenishment. It is also necessary to control the concentration of organic carbon and the rate of recharge, which would provide guidance for other similar projects.

A coupled optimization of groundwater remediation alternatives screening under health risk assessment: An application to a petroleum-contaminated site in a typical cold industrial region in Northeastern China.

Contaminated sites have been recognized as posing serious comprehensive social and environmental issues and have earned worldwide attention. China is becoming one of the largest contaminated sites remediation markets in the world and the contaminated sites in northeastern China need to rehabilitate urgently. However, remediation planning is often hindered by high financial costs resulting from incomplete assessments of pollution and inappropriate remediation plans. In-depth contaminated site assessments can provide the necessary baseline data for remediation alternatives screening. Therefore, risk assessments and remediation decisions will play crucial roles in the rehabilitation and reconstruction of contaminated sites in China. The main objectives of this study were to present a novel method for health risk assessment (HRA) and to demonstrate a multicriteria decision analysis (MCDA) based on this method to select the most suitable remediation alternatives of groundwater and to prioritize management of contaminated site. To demonstrate the HRA and MCDA processes, a typical contaminated site in Longtan, Jilin province, China, was used. The results of this research indicated that Benzene (PhH) and 1,2-Dichloroethylene (1,2-DCE) were the main organic pollutants and the vanillin plant in the north of the site was main pollution source. Pollution migrated from the north to the south and the health risk range in winter was significantly greater than in summer. Four remediation alternatives were proposed on the basis of the HRA results. The MCDA results showed that PRB was the most suitable technology for integrating the relevant environmental, social, economic, and technical aspects required for remediation. This study may help responsible agencies to strengthen local risk-based program screening frameworks for contaminated sites, to promote reconstruction projects, and to increase local public confidence of contaminated sites remediation.

Influence of hydraulic gradient and temperature on the migration of E. coli in saturated porous media during bank filtration: a case study at the Second Songhua River, Songyuan, Northeastern China.

River bank filtration can effectively reduce the number of pathogenic microorganisms infiltrating into groundwater from surface water. Groundwater seepage velocity and temperature are considered to be important factors affecting the process, but the magnitude and mechanism of their impacts have not been clear for a long time. Based on the actual monitoring data of the Escherichia coli concentrations and soil samples of Second Songhua riverside source area, the migration of E. coli in saturated porous media under different velocities and different temperatures was studied using saturated soil column transport experiments. Concurrently, the migration characteristics of E. coli in the riverside source area were replicated by mathematical simulation. According to the field monitoring results, the concentration of E. coli decreased in the riverbank infiltration zone, and the removal rate was greater than 96%. The column experimental results showed that the lower the flow velocity was and the higher the temperature was, the greater the removal rate of E. coli was. And the flow velocity was the main factor affecting the removal of E. Coli. The mathematical simulation results showed that under the conditions of the largest hydraulic gradient (20%) and the highest concentration of E. coli (2500 MPN/100 mL) in river water, the safe exploitation distance of groundwater that did not cause a risk of E. coli pollution was more than 7 m away from the river bank. These findings are expected to provide a scientific basis for the design of water intake schemes and the optimization of mining technology.

Preparation and performance of manganese-oxide-coated zeolite for the removal of manganese-contamination in groundwater.

A promising and easily prepared catalytic filler media, manganese-oxide-coated zeolite (MOCZ), for the removal of Mn (II) contamination in groundwater was studied. The optimal condition for MOCZ preparation was given as follows: acid activation of zeolite with 5% HCl mass percent for 12 h, then soaking of acid-activated zeolite with 7% KMnO4 mass percent for 8 h, and finally calcination at 300°C for 5 h. Acid activation significantly enlarged the specific surface area of the zeolite (>79 m2 g-1), subsequently enhancing the coating of manganese oxides onto the surface of the zeolite. This was further supported by the manganese-to-zeolite ratio (γMn) and Energy dispersive analysis-mapping. The γMn was over 12.26 mg Mn g-1 zeolite, representing more active sites for the adsorption and catalytic-oxidation of Mn (II). As such, great performance of Mn (II) removal by MOCZ was obtained in the filter experiment. An estimated 98-100% removal efficiency of Mn (II) was achieved in a greatly short startup time (only 2 h). During the filtration process, newborn flocculent manganese oxides with a mixed-valence of manganese (Mn (II) and Mn (IV)) were generated on the MOCZ surface, further facilitating the adsorption and catalytic-oxidation of Mn (II). The filter with MOCZ as adsorbent had a great performance on the Mn (II) removal in a wide range of hydraulic retention time (HRT) (4-40 min), particularly in a short HRT. Besides, the filter prolonged the filtration period (60 days), which would significantly reduce the frequency of backwash. Thus, it could be concluded that MOCZ prepared in this study showed a good performance in terms of Mn (II) removal in waterworks, especially small waterworks in the villages/towns.

Selenium (Se) uptake and dynamic changes of Se content in soil-plant systems.

In this study, we collected crop plants and associated soil samples and determined these for selenium (Se) content to analyze the uptake, enrichment, and translocation of Se in the different soil-plant systems of an agricultural production area, elucidate the dynamic mechanisms relating to Se content in plants and soil during different growth periods, and screen plants for high Se enrichment ability. Bioconcentration factor determinations indicated that the grains of rice have the strongest Se enrichment ability, followed by soybean and corn. Translocation factor analysis indicated that the grains of rice and corn have similar low translocation abilities for Se compared with soybean. Within the study area, the Se content in plants was closely related to the soil available Se content and varied considerably among different growth periods and plant organs. This study provides a theoretical basis for the development and utilization of local agricultural products.

An adaptive Kriging surrogate method for efficient joint estimation of hydraulic and biochemical parameters in reactive transport modeling.

Groundwater reactive transport models that consider the coupling of hydraulic and biochemical processes are vital tools for predicting the fate of groundwater contaminants and effective groundwater management. The models involve a large number of parameters whose specification greatly affects the model performance. Thus model parameters calibration is crucial to its successful application. The Bayesian inference framework implemented by Markov chain Monte Carlo (MCMC) sampling provides a comprehensive framework to estimate the model parameters. However, its application is hampered by the large computational requirements caused by repeated evaluations of the model in MCMC sampling. This study develops an adaptive Kriging-based MCMC method to overcome the bottleneck of Bayesian inference by replacing the simulation model with a computationally inexpensive Kriging surrogate model. In the adaptive Kriging-based MCMC method, instead of constructing a globally accurate surrogate of the simulation model, we sequentially build a locally accurate surrogate with an iterative refinement to the high probability regions. The performance of the proposed method is demonstrated using a synthetic groundwater reactive transport model for describing sequential Kinetic degradation of Tetrachloroethene (PCE), whose hydraulic and biochemical parameters are jointly estimated. The results suggest that the adaptive Kriging-based MCMC method is able to achieve an accurate Bayesian inference with a hundredfold reduction in the computational cost compared to the conventional MCMC method.

Effectiveness and mechanism of natural attenuation at a petroleum-hydrocarbon contaminated site.

This study applied an integrated method for evaluating the effectiveness and mechanism of natural attenuation (NA) of petroleum-hydrocarbon contaminated groundwater. Site groundwater and soil samples were analysed to characterize spatial and temporal variations in petroleum hydrocarbons, geochemical indicators, microbial diversity and isotopes. The results showed that the area of petroleum hydrocarbon contamination plume decreased almost 60% in four years, indicating the presence of natural attenuation. The 14C content and sequence analysis indicate that there are more relatively 'old' HCO3- that have been produced from petroleum hydrocarbons in the upgradient portion of the contaminated plume, confirming that intrinsic biodegradation was the major factor limiting spread of the contaminated plume. The main degradation mechanisms were identified as sulfate reduction and methanogenesis based on the following: (1) more SO42- have been consumed in the contamination source than downgradient, and the δ34S values in the resident SO42- were also more enriched in the contamination source, (2) production of more CH4 in the contamination source with the δ13C values for CH4 was much lower than that of CO2, and the fractionation factor was 1.030-1.046. The results of this study provide significant insight for applying natural attenuation and enhanced bioremediation as alternative options for remediation of petroleum-hydrocarbon contaminated sites.

Biogeochemical zonation of sulfur during the discharge of groundwater to lake in desert plateau (Dakebo Lake, NW China).

As one of the important elements of controlling the redox system within the hyporheic and hypolentic zone, sulfur is involved in a series of complex biogeochemical processes such as carbon cycle, water acidification, formation of iron and manganese minerals, redox processes of trace metal elements and a series of important ecological processes. Previous studies on biogeochemistry of the hyporheic and hypolentic zones mostly concentrated on nutrients of nitrogen and phosphorus, heavy metals and other pollutants. Systematic study of biogeochemical behavior of sulfur and its main controlling factors within the lake hypolentic zone is very urgent and important. In this paper, a typical desert plateau lake, Dakebo Lake in northwestern China, was taken for example within which redox zonation and biogeochemical characteristics of sulfur affected by hydrodynamic conditions were studied based on not only traditional hydrochemical analysis, but also environmental isotope evidence. In the lake hypolentic zone of the study area, due to the different hydrodynamic conditions, vertical profile of sulfur species and environmental parameters differ at the two sites of the lake (western side and center). Reduction of sulfate, deposition and oxidation of sulfide, dissolution and precipitation of sulfur-bearing minerals occurred are responded well to Eh, dissolved oxygen, pH, organic carbon and microorganism according to which the lake hypolentic zone can be divided into reduced zone containing H2S, reduced zone containing no H2S, transition zone and oxidized zone. The results of this study provide valuable insights for understanding sulfur conversion processes and sulfur biogeochemical zonation within a lake hypolentic zone in an extreme plateau arid environment and for protecting the lake-wetland ecosystem in arid and semiarid regions.

Thermally activated persulfate oxidation of NAPL chlorinated organic compounds: effect of soil composition on oxidant demand in different soil-persulfate systems.

This study investigates the interaction of persulfate with soil components and chlorinated volatile organic compounds (CVOCs), using thermally activated persulfate oxidation in three soil types: high sand content; high clay content; and paddy field soil. The effect of soil composition on the available oxidant demand and CVOC removal rate was evaluated. Results suggest that the treatment efficiency of CVOCs in soil can be ranked as follows: cis-1,2-dichloroethene > trichloroethylene > 1,2-dichloroethane > 1,1,1-trichloroethane. The reactions of soil components with persulfate, shown by the reduction in soil phase natural organics and mineral content, occurred in parallel with persulfate oxidation of CVOCs. Natural oxidant demand from the reaction of soil components with persulfate exerted a large relative contribution to the total oxidant demand. The main influencing factor in oxidant demand in paddy-soil-persulfate systems was natural organics, rather than mineral content as seen with sand and clay soil types exposed to the persulfate system. The competition between CVOCs and soil components for oxidation by persulfate indicates that soil composition exhibits a considerable influence on the available oxidant demand and CVOC removal efficiency. Therefore, soil composition of natural organics and mineral content is a critical factor in estimating the oxidation efficiency of in-situ remediation systems.

Novel Bi2 WO6 -coupled Fe3 O4 Magnetic Photocatalysts: Preparation, Characterization and Photodegradation of Tetracycline Hydrochloride.

Novel Bi2 WO6 -coupled Fe3 O4 magnetic photocatalysts with excellent and stable photocatalytic activity for degrading tetracycline hydrochloride and RhB were successfully synthesized via a facile solvothermal route. Through the characterization of the as-prepared magnetic photocatalysts by X-ray diffractometry, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-Vis diffuse reflectance spectra, it was found that the as-prepared magnetic photocatalysts were synthesized by the coupling of Bi2 WO6 and Fe3 O4 , and introduction of appropriated Fe3 O4 can improve nanospheres morphology and visible-light response. Among them, BFe2 (0.16% Fe3 O4 ) exhibited the best photocatalytic activity for degradation of tetracycline hydrochloride (TCH), reaching 81.53% after 90 min. Meanwhile, the as-prepared magnetic photocatalysts showed great separation and recycle property. Moreover, the results of electrochemical impedance spectroscopy demonstrated that the well conductivity of Fe3 O4 can promote photogenerated charge carriers transfer and inhibit recombination of electron-hole pairs, so that Bi2 WO6 /Fe3 O4 exhibited enhanced photocatalytic activity on degradation of TCH and RhB. Hence, this work provides a principle method to synthesize Bi2 WO6 /Fe3 O4 with excellent photocatalytic performance for actual application, in addition, it showed that introduction of Fe3 O4 not only can provide magnetism, but also can enhance photocatalytic activity of Bi2 WO6 /Fe3 O4 magnetic photocatalysts.